ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

Published monthly
 

Catalysts for vinyl chloride. III. The conditions for development of side reaction products

J. Janda and A. Vanko

Research Institute for Acetylenchemistry, Nováky

 

Abstract: cf. C.A. 52, 1049a. Vinyl chloride (I), synthesized above 150° on a catalyst prepd. by the impregnation of active C with HgCl2, contains from the products boiling above 20°, MeCHCl2 (II), trans-(ClCH:)2 (III), AcH (IV) and in smaller amts. cis-(ClCH:)2 (V), ClCH2CHCl2 (VI), and CH2:CCl2 (VII). In the reaction system for the formation of IV and VII, H2O is necessary. The formation of III, V, and VII is dependent on the amt. of free Cl in HCl entering the reaction. In the reaction of HCl with I, the formation of II, III and VI, and part of I and IV is catalyzed by the active C, while the other part of I and IV, VII and V is catalyzed by HgCl2.

Full paper in Portable Document Format: 1111a660.pdf (in Slovak)

 

Chemical Papers 11 (11) 660–668 (1957)

Friday, March 29, 2024

IMPACT FACTOR 2021
2.146
SCImago Journal Rank 2021
0.365
SEARCH
Advanced
VOLUMES
European Symposium on Analytical Spectrometry ESAS 2022
© 2024 Chemical Papers