ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

Published monthly
 

A novel tetraphenylethylene-functionalized arylimidazole AIEgen for detections of picric acid and Cu2+

Yin, Yuanye, Zhang, Shuaishuai, He, Xuan, Xu, Xiao, Zhang, Gaobin, Yang, Longmei, Kong, Lin, Yang, and Jiaxiang

Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functional Materials, College of Chemistry and Chemical Engineering, Anhui University, Hefei, People’s Republic of China

 

E-mail: gbzhang@hpu.edu.cn

Received: 28 March 2021  Accepted: 16 July 2021

Abstract:

Abstract

A novel tetraphenylethylene (TPE)-functionalized arylimidazole derivative (HTPEAIM) has been designed and synthesized. The structure was characterized by FT-IR, HR-MS, 1H and 13C NMR. The photophysical properties were investigated by UV–vis absorption and PL spectra. HTPEAIM exhibited excellent aggregation-induced emission (AIE) property that it was non-emission in organic solution and with high fluorescence in aggregation state as the restriction of intramolecular motions (RIMs). Moreover, HTPEAIM could be a fluorogenic probe for sensing picric acid (PA) and Cu2+ in the aqueous environment. Since the proton binding capacity of the N atom of the imidazole group and the donor–acceptor interactions, HTPEAIM was able to sensitively and selectively detect PA through the synergistic effects of photoinduced energy transfer (PET) and fluorescence resonance energy transfer (FRET) with a limit of detection (LOD) of 0.99 μM. Meanwhile, driving by the metal binding ability of the pincer-like structure of hydroxyl and imidazole group, HTPEAIM was used for sensing Cu2+ in the aqueous environment. The response mechanism was systemically studied, and the results showed that the stable Cu(HTPEAIM)2 complex was formed and that induced the fluorescence highly quenching to obtain a low LOD of 34.8 nM.

Graphical Abstract

Keywords: Aggregation-induced emission; Fluorescence probe; PA; Cu2+

Full paper is available at www.springerlink.com.

DOI: 10.1007/s11696-021-01795-5

 

Chemical Papers 75 (12) 6297–6306 (2021)

Sunday, January 23, 2022

IMPACT FACTOR 2020
2.097
SCImago Journal Rank 2020
0.344
SEARCH
Advanced
VOLUMES
XXVIII. International Conference on Coordination and Bioinorganic Chemistry
© 2022 Chemical Papers