ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

Published monthly
 

Enhanced CO2 uptake of mesoporous activated carbon derived from chitosan/casein coacervate

K. Malini, D. Selvakumar, and N. S. Kumar

Defence Bioengineering and Electromedical Laboratory (DEBEL), DRDO, Bangalore, India

 

E-mail: dhanaselva@gmail.com

Received: 19 October 2022  Accepted: 4 March 2023

Abstract:

Preparation of nitrogen-doped porous activated carbon materials gained much importance in recent years due to their enhanced CO2 adsorption properties and CO2/N2 selectivity as against undoped counterparts. In this study, N-doped activated carbon macrospheres were prepared by carbonization of casein-coated chitosan macrospheres obtained by coacervation method, where chitosan serves as a nitrogen containing carbon (C/N) precursor and casein serves as an additional polymeric nitrogen source. Uncoated chitosan macrospheres were also prepared in NaOH solution for comparative studies. SEM–EDS, CHN analysis, BET surface area analysis, Raman, FTIR, XRD and XPS were performed on both samples to compare the textural characteristics of the activated carbons prepared. Thermal analysis using TGA and DTG revealed that coacervated sample possessed improved thermal stability. The CO2 adsorption studies showed an enhanced adsorption capacity for the activated carbon prepared from chitosan/casein macrospheres (123.57 mg/g) than for the activated carbon from chitosan/NaOH macrospheres (97.98 mg/g) at 25 °C and 1 bar. The activated carbon prepared from chitosan/casein macrospheres exhibited an excellent CO2/N2 selectivity. Furthermore, a steady CO2 uptake studied up to 5 cycles indicates the material is thermally stable and reusable without deterioration in CO2 adsorption capacity.

Graphical abstract

Keywords: Chitosan; Casein; Coacervate; Activated carbon; CO2 adsorption

Full paper is available at www.springerlink.com.

DOI: 10.1007/s11696-023-02768-6

 

Chemical Papers 77 (8) 4179–4192 (2023)

Friday, May 24, 2024

IMPACT FACTOR 2021
2.146
SCImago Journal Rank 2021
0.365
SEARCH
Advanced
VOLUMES
European Symposium on Analytical Spectrometry ESAS 2022
© 2024 Chemical Papers