ISSN print edition: 0366-6352
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Differences in the Mechanism of Influence of Organic Cation and Anion Radicals on the Cathodic Processes in Chloroaluminate Melt

N. Tumanova, L. Bogdanovich, and P. Rudenok

Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev-142, 252680 Ukraine

 

Abstract: The formation of stable ion-radicals of some organic compounds during the electrolysis of chloroaluminate melt has been shown. The cathodic discharge of cadmium, cobalt ions is stimulated by the ion-radicals formation. The influence of cation radicals is catalytic in nature, and the degree of stimulation is higher than that of anion radicals, and is caused by their adsorption on the Pt-electrode surface.

Full paper in Portable Document Format: 522a80.pdf

 

Chemical Papers 52 (2) 80–85 (1998)

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