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Comparison of Three Methods of the Conversion of 1-Deoxy-l-nitroalditols to the Corresponding Aldoses

D.-P. Pham-Huu, M. Petrušová, and L. Petruš

Institute of Chemistry, Slovak Academy of Sciences, SK-842 38 Bratislava

 

Abstract: Ozonolysis, peroxomolybdate oxidation, and the treatment with sulfuric acid as three relatively simple methods of the conversion of 1-deoxyalditol-1-nitronates to the corresponding aldoses were mutually compared. The yields and complexity of the methods applied to the synthesis of D-glycero-D-galacto-heptose and D-glycero-D-talo-heptose from D-mannose are presented and discussed.

Full paper in Portable Document Format: 524a235.pdf

 

Chemical Papers 52 (4) 235–237 (1998)

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