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Structure of Disodium cis-Bis(iminodiacetato)cobalt(II) Hexahydrate

F. Valach, N. N. Hoang, and I. LukeŇ°

Department of Chemical Physics, Faculty of Chemical Technology, Slovak Technical University, SK-812 31 Bratislava

 

Abstract: The crystal structure of Na2[Co(Hida)2]. 6H2O (Hida = iminodiacetato) contains discrete units [Co(Hida)2]2-, ions Na+, and water molecules. The pseudooctahedral coordination of Co(II) is created by four O atoms (the bond lengths Co-O are 0.202(1), 0.203(1), 0.207(1), and 0.210(1) nm) and two N atoms of two Hida ligands (bond lengths Co-N are 0.211(2) and 0.214(2) nm). The cations Na+ are pseudooctahedrally surrounded by four water O atoms and two carboxyl O atoms from the different units [Co(Hida)2]2-.

Full paper in Portable Document Format: 503a115.pdf

 

Chemical Papers 50 (3) 115–120 (1996)

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