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Thermal Properties of Complexes M(NH3)2[Ag(CN)2]2 (M(ll) = Ni, Cu, Cd)

J. Chomič, J. Černák, I. Potočňák, I. Zvereva, and N. Savelieva

Department of Inorganic Chemistry, Faculty of Natural Sciences, P. J. Šafárik University, CS-041 54 Košice

 

Abstract: Complexes of composition M(NH3)2[Ag(CN)2]2, where M = Ni (NiA), Cu (CuA), Cd (CdA), have been prepared and identified by infrared and electron spectroscopy and by magnetic susceptibility measurements. Thermal stability and stoichiometry of thermal decomposition were investigated by using a derivatograph. The intermediates of thermal decomposition were identified by IR spectroscopy and X-ray powder diffraction. The results showed that the thermal stability increased in the order CuA, CdA, NiA.

Full paper in Portable Document Format: 473a175.pdf

 

Chemical Papers 47 (3) 175–178 (1993)

Wednesday, October 16, 2019

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