ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Thermal Properties of Complexes M(NH₃)₂[Ag(CN)₂]₂ (M(ll) = Ni, Cu, Cd)

J. Chomič, J. Černák, I. Potočňák, I. Zvereva, and N. Savelieva

Department of Inorganic Chemistry, Faculty of Natural Sciences, P. J. Šafárik University, CS-041 54 Košice

Abstract: Complexes of composition M(NH₃)₂[Ag(CN)₂]₂, where M = Ni (NiA), Cu (CuA), Cd (CdA), have been prepared and identified by infrared and electron spectroscopy and by magnetic susceptibility measurements. Thermal stability and stoichiometry of thermal decomposition were investigated by using a derivatograph. The intermediates of thermal decomposition were identified by IR spectroscopy and X-ray powder diffraction. The results showed that the thermal stability increased in the order CuA, CdA, NiA.

Full paper in Portable Document Format: 473a175.pdf

Chemical Papers 47 (3) 175–178 (1993)