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Reactions of Ferrocenecarboxylic Acid and ω- Ferrocenyl-ω-oxoalkanoic Acids with 2-Aminothiophenol

M. Salisšová, M. Prokešová, M. Kubričanová, and Š. Toma

Department of Organic Chemistry, Faculty of Natural Sciences, Comenius University, CS-842 15 Bratislava

 

Abstract: Reactions of the title compounds with 2-aminothiophenol have been studied. Ferrocenecarboxylic acid afforded 2-ferrocenylbenzothiazole, ω-ferrocenyl-ω-oxoalkanoic acids, depending on the number n of -CH2- groups, gave either 2-(ω-ferrocenyl-ω-oxoalkanoyl)benzothiazoles (n = 3, 4), or derivatives of ferrocenylbenzothiazocine (n = 2), resp. ferrocenylbenzothiazonine (n = 3). Some reactions of 2-ferrocenylbenzothiazole were studied, too.

Full paper in Portable Document Format: 473a183.pdf

 

Chemical Papers 47 (3) 183–185 (1993)

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