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EPR Spectrum of Radicals from Thermal Decomposition of 1,1,2,2-Tetraphenyl-1,2-bis(trimethylsiloxy)ethane

J. Plaček, F. Szöcs, and A. Bledzki

Polymer Institute, Slovak Academy of Sciences, CS-842 36 Bratislava

 

Abstract: Free radicals generated by thermal decomposition of tetraphenyl-1,2-bis(trimethylsiloxy)ethane were studied by EPR spectroscopy. The maximum amount of free radicals was obtained at temperature 403 K. Hyperfine splitting constants of diphenyl-(trimethylsiloxy)methyl radicals were determined and a good agreement between experimental and simulated EPR spectra has been found.

Full paper in Portable Document Format: 463a182.pdf

 

Chemical Papers 46 (3) 182–183 (1992)

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