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ISSN electronic edition: 1336-9075
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Redox Reactions of Iron(III) Chloro and Isothiocyanato Complexes with Triphenylstilbene and Triphenylbismuthine in Acetonitrile

V. Vančová and I. Ondrejkovičová

Department of Inorganic Chemistry, Faculty of Chemical Technology, Slovak Technical University, CS-812 37 Bratislava

 

Abstract: The reduction of Fe(III) to Fe(II) in the systems FeX3-EPh3-acetonitrile (X = Cl, NCS; E = Sb, Bi; Ph = phenyl) occurs at ambient temperature. Fe(II)-Fe(III) complexes of the composition [Fe(NCCH3)6][FeX4]2 are formed and the ligands EPh3 are oxidized under formation of XEPh3.

Full paper in Portable Document Format: 466a382.pdf

 

Chemical Papers 46 (6) 382–384 (1992)

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