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Phase-transfer catalyzed synthesis of α-ferrocenylmethylenecycloalkanones

M. Sališová, M. Puciová, V.N. Postnov, and Š. Toma

Department of Organic Chemistry, Faculty of Natural Sciences, Comenius University, CS-842 15 Bratislava

 

Abstract: Synthesis of α-ferrocenylmethylenecycloalkanones from cyclic ketones and ferrocenecarbaldehyde under phase transfer catalysis is described. E and Z isomers of 3-ferrocenylmethylene-l,7,7-trimethylbicyclo[2,2,l]heptan-2-one were easily separated by the column chromatography.

Full paper in Portable Document Format: 442a201.pdf

 

Chemical Papers 44 (2) 201–207 (1990)

Tuesday, April 16, 2024

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