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Physicochemical properties of the molten system Na3AlF6-K3AlF6-Al2O3. 1. The temperature of primary crystallization

P. Fellner, M. Chrenková, J. Gabčová, and K. Matiašovský

Department of Inorganic Technology, Faculty of Chemical Technology, Slovak Technical University, CS-812 37 Bratislava

 

Abstract: The results of investigation of the temperature of primary crystallization of the system Na3AlF6-K3AlF6-Al2O3  are presented. The experimental data are compared with calculated temperatures of primary crystallization using the "universal model". It follows that alumina dissolved in molten  K3AlF6 forms another type of oxofluoride species than are those which have been reported for molten Na3AlF6-Al2O3   mixtures at comparable con­centration.

Full paper in Portable Document Format: 445a677.pdf

 

Chemical Papers 44 (5) 677–684 (1990)

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