ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Reactions of saccharides catalyzed by molybdate ions. 43. ⁹⁵Mo-NMR spectra of the molybdate complexes of alditols and aldoses

M. Matulová and V. Bílik

Institute of Chemistry, Slovak Academy of Sciences, CS-842 38 Bratislava

Abstract: The tetradentate molybdate complexes of alditols with the sickle arrange­ment of the carbon chain in the site of complexation, formed in the aqueous solutions of ammonium molybdate have in the ⁹⁵ Mo NMR spectra the signals with chemical shifts in the interval of 25—34 ppm, while those with the zig-zag arrangement in the interval of 18—20 ppm. Aldoses of the homomorphous series of lyxose, ribose, and arabinose in the molybdate complexes display ⁹⁵Mo NMR spectra which are characteristic of each homomorphous series.

Full paper in Portable Document Format: 445a703.pdf

Chemical Papers 44 (5) 703–709 (1990)