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Reactions of saccharides catalyzed by molybdate ions. 43. 95Mo-NMR spectra of the molybdate complexes of alditols and aldoses

M. Matulová and V. Bílik

Institute of Chemistry, Slovak Academy of Sciences, CS-842 38 Bratislava

 

Abstract: The tetradentate molybdate complexes of alditols with the sickle arrange­ment of the carbon chain in the site of complexation, formed in the aqueous solutions of ammonium molybdate have in the 95 Mo NMR spectra the signals with chemical shifts in the interval of 25—34 ppm, while those with the zig-zag arrangement in the interval of 18—20 ppm. Aldoses of the homomorphous series of lyxose, ribose, and arabinose in the molybdate complexes display 95Mo NMR spectra which are characteristic of each homomorphous series.

Full paper in Portable Document Format: 445a703.pdf

 

Chemical Papers 44 (5) 703–709 (1990)

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