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Charge distribution in model organic polymers

P. Pelikán, L. Lapčík, and D. Marianiová

Department of Physical Chemistry, Faculty of Chemical Technology, Slovak Technical University, CS-81237 Bratislava

 

Abstract: The electron structure, i.e. the distribution of Wiberg indices of respective bonds and the charge values of individual atoms, contained in the model structures of polymer compounds of the poly(p-phenylene), poly(p-phenylene oxide), poly(p-phenylene sulfide), poly(p-phenylene selenide), poly(2,6-dimethylphenylene oxide), polyazomethine, cyclic polynitrogen and poly(dibenzofuran) types of the system, have been studied. In the case of thermal polyacrylonitrile destruction the cyclic polynitrogen radical developed has been found to have the most favourable electron distribution ensuring all assumptions for the higher electron conductivity.

Full paper in Portable Document Format: 432a229.pdf

 

Chemical Papers 43 (2) 229–237 (1989)

Thursday, March 28, 2024

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