ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Reactions of saccharides catalyzed by molybdate ions. 38. NMR spectra of alditols in molybdate complexes
M. Matulová, V. Bílik, and J. Alfőldi
Institute of Chemistry, Centre for Chemical Research,
Slovak Academy of Sciences, CS-84238 Bratislava
Abstract: The formation of complexes of 17 selected alditols with ammonium
molybdate in aqueous solutions was investigated by 1H and 13C NMR
spectroscopy. Alditols form four types of binuclear molybdate complexes in
which they serve as tetradentate donors with four vicinal hydroxyl groups.
In two types of alditol-molybdate complexes the alditol carbon chain remains in the shape close to a zig-zag arrangement. In other two types of
complexes the alditol carbon chain is forced to a sickle arrangement.
Full paper in Portable Document Format: 433a403.pdf
Chemical Papers 43 (3) 403–414 (1989)