ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Calculations in chemical thermodynamics

J. Skotnický

Abstract: In order to determine the characteristic values of the chemical systems: entropy, enthalpy^ and Gibbs energy a new calculation method is proposed, theoretically dealing with the curvature of the line expressing a dependence of RT\n К from temperature T. This line is substituted with a direct line, which is led through the empirical points by means of equalizing calcula­tions. Applied method of putting In K(y) in to dependence from l/T(x) is not suitable for the larger temperature intervals.

Full paper in Portable Document Format: 411a35.pdf (in German)

Chemical Papers 41 (1) 35–48 (1987)