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Enthalpies of solution of methoxy and ethoxy end group oligomers of poly(ethylene glycol) in binary solvent water - dimethylformamide  Study of hydrophobic hydration

P. Cifra and A. Romanov

Polymer Institute, Centre for Chemical Research, Slovak Academy of Sciences, CS-84236 Bratislava

 

Abstract: Deviations from ideality in solution enthalpies of solutes are explained by hydrophobic hydration. The extent of this type of hydration is expressed by means of two methods. Experimental results obey previously proposed group contribution concept for evaluation of enthalpic effect of hydropho bic hydration and the obtained methylene group contribution is in good agreement with that obtained previously from the data on other hydropho­bic homologous series.

Full paper in Portable Document Format: 413a395.pdf

 

Chemical Papers 41 (3) 395–400 (1987)

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