ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Synthesis and thermal investigation of solid mixed-ligand chlorotitanium(III) complexes containing acetonitrile and aliphatic-alcohols

M. Kohútová and M. Zikmund

Institute of Inorganic Chemistry, Centre for Chemical Research, Slovak Academy of Sciences, CS-842 36 Bratislava

 

Abstract: The mixed-ligand chlorotitanium(III) complexes containing acetonitrile and aliphatic alcohols were prepared by the reaction of solid TiCl3(CH3CN) with aliphatic alcohols (CnH2n+iOH, n = 1—4) in stoichiometric ratio and in medium of noncoordinating solvent. Their thermal properties were investigated in the temperature range 20 °C—400 °C. It has been found that in the course of thermal treating the alcoholysis of corresponding alcohol takes place and the intermediates involving alkoxo groups are formed.

Full paper in Portable Document Format: 406a721.pdf

 

Chemical Papers 40 (6) 721–726 (1986)

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