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ISSN electronic edition: 1336-9075
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Influence of auxiliary solvents on tetracyano complex-compounds

A. Sopková, F. Kaľavský, M. Šingliar, J. Bubanec, and P. Králik

Department of Inorganic Chemistry, Faculty of Natural Sciences, P. J. Šafárik University, CS-041 54 Košice

 

Abstract: The interaction of the tetracyano complexes Cu(NH3)m Ni(CN)4 .nH20 and ZnNi(CN)4 . nH20 with water, methanol, hexane, cyclohexane, benzene, 3-methylpyridine, and pyridine was investigated. All these compounds influence the ability of sorption of tetracyano complexes and the last two solvents also bring about changes in their structure. The interaction of all these solvents with tetracyano complexes gives rise to a stationary phase which makes it possible to perform a better chromatographic separation of different organic mixtures at increased temperatures.

Full paper in Portable Document Format: 406a735.pdf

 

Chemical Papers 40 (6) 735–745 (1986)

Tuesday, June 25, 2024

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