ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Comparison of polymeric and ceramic membranes performance in the process of micellar enhanced ultrafiltration of cadmium(II) ions from aqueous solutions

Katarzyna Staszak, Zofia Karaś, and Karolina Jaworska

Institute of Technology and Chemical Engineering, Poznan University of Technology, Pl. M. Skłodowskiej-Curie 2, 60-965, Poznań, Poland

E-mail: Katarzyna.Staszak@put.poznan.pl

Abstract: A comparison of polymeric and ceramic membranes in the ultrafiltration process was studied and presented. This study was conducted on the separation of cadmium(II) ions, with particular reference to parameters such as hydrodynamic permeability coefficient, membrane fouling, amount of surfactant in the permeate, efficiency, and effectiveness of the process. The effect of ionic (SDS) and non-ionic (Rofam 10) surfactants or their mixture was investigated. The hydrodynamic permeability coefficient of the ceramic membrane was found to be much lower in comparison to those of the polymeric ones (1.69 × 10⁻⁷ m³ h⁻¹ m⁻² Pa⁻¹, 5.66 × 10⁻⁷ m³ h⁻¹ m⁻² Pa⁻¹, and 9.26 × 10⁻⁷ m³ h⁻¹ m⁻² Pa⁻¹ for ceramic, CA, and PVDF, respectively). However, filtration of the surfactants solutions did not cause permanent blocking of pores and the surface of the ceramic membrane in contrast to the polymeric ones. No significant differences in surfactants permeation through the membranes tested were observed. Concentration of the surfactant in the permeate was lower than 1 CMC for the Rofam 10 solution and exceeded the CMC by about 40 % for the SDS solution. Better separation properties of polymer membranes for the separation of cadmium(II) ions from micellar systems were identified.

Keywords: ultrafiltration – ceramic and polymeric membrane – cadmium(II) ion

Full paper is available at www.springerlink.com.

DOI: 10.2478/s11696-012-0280-x

Chemical Papers 67 (4) 380–388 (2013)