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Angular overlap treatment of the electronic spectra of the chlorotitanium(III) complexes containing tetrahydrofuran and acetonitrile

G. Plesch

Institute of Inorganic Chemistry, Centre for Chemical Research, Slovak Academy of Sciences, CS-842 36 Bratislava

 

Abstract: The electronic spectra of the distorted octahedral complexes TiCl3(C4H8O)3, TiCl3(C4H8O)2(CH3CN), and TiCl3(CH3CN)3 were interpreted with the aid of the angular overlap model using the transferability assumption for the single ligand parameters. The σ and π bonding parameters eλ for the Ti(III)-ligand bonds were detd. The following 2-dimensional spectrochem. series for Ti(III) complexes was established: eσ: Cl < C4H8O < CH3CN and eπ: CH3CN < C4H8O < Cl.

Full paper in Portable Document Format: 381a33.pdf

 

Chemical Papers 38 (1) 33–40 (1984)

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