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Kinetics of reactions of O-benzoylbenzaldoxime derivatives in acetic acid

J. Mollin and A. Holakovská

Department of Inorganic and Physical Chemistry, Faculty of Natural Sciences, Palacký University, CS-771 46 Olomouc

 

Abstract: The rate of E-Z isomerization of O-acylaldoximes in glacial HOAc has been followed by using spectral data. The decrease of O-acylaldoxime with time was established from the decrease of the limit current of the polarog. wave. Gas chromatog. and liq. chromatog. were applied to det. the concn. of the reaction products. The O-acylaldoximes also undergo acid-catalyzed cleavage to give nitriles.

Full paper in Portable Document Format: 375a633.pdf

 

Chemical Papers 37 (5) 633–638 (1983)

Tuesday, June 18, 2024

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