ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Thermodynamics of phase equilibriums in systems with polymorphic transitions. V. Systems in which continuous liquid and continuous solid solutions coexist and which contain complex compounds in the subsolidus region
I. Koštenská and M. Malinovský
Department of Inorganic Technology, Slovak Technical University,
812 37 Bratislava
Abstract: Thermodynamic analysis of three characteristic cases of phase equilibria in
the systems of given type was carried out. The following cases are discussed: 1.
there is an explicit maximum (a distectoid point) on the curve of monovariant
equilibrium of complex compound; 2. this maximum exists only as an implicit
one; 3. the complex compound has not its own curve of monovariant phase
Rules which determine the values of slopes of tangents in remarkable points
of the curves of monovariant equilibrium in these phase diagrams are derived.
Full paper in Portable Document Format: 365a599.pdf
Chemical Papers 36 (5) 599–604 (1982)