ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

Published monthly
 

Isomerizations of C8-C12 cycloalkadienes catalyzed by titanocene derivatives

K. Mach, F. Tureček, V. Hanuš, L. Petrusová, H. Antropiusová, A. Dosedlová, and P. Sedmera

J. Heyrovský Institute of Physical Chemistry and Electrochemistry, Czechoslovak Academy of Sciences, 121 38 Prague

 

Abstract:  The interaction of Cp2TiH containing catalyst with C10 and C12 cycloal­kadienes yields Ai-cycloalken-l-ylbis(cyclopentadienyl)titanium(III) com­pounds (n= 2—6) but only the stable allyl compounds are characterized by e.s.r. and electronic absorption spectra. All of them cooperate in transforming the substrate by stepwise double bond shifts into the equilibrium mixture of isomers. The conjugated cycloalkadienes constituted minor components in C10 and C12 equilibrium mixtures while in C8 diene it was the only product.

Full paper in Portable Document Format: 362a191.pdf

 

Chemical Papers 36 (2) 191–200 (1982)

Wednesday, April 24, 2024

IMPACT FACTOR 2021
2.146
SCImago Journal Rank 2021
0.365
SEARCH
Advanced
VOLUMES
European Symposium on Analytical Spectrometry ESAS 2022
© 2024 Chemical Papers