ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

 Influence of temperature, vanadium concentration, and degree of solution acidification on composition of the solid products V. System sodium metavanadate—thallium(I) acetate—acetic acid (nitric acid)—water

D. Pápežová and Ľ. Žurková

Department of Inorganic Chemistry, Faculty of Natural Sciences, Komenský University, 816 31 Bratislava

Abstract:  The influence of concentration of starting solutions, acidification degree, temperature, properties of the acid used, and length of the reaction time on composition of the solid products arising in the systems NaVO₃—CH₃COOTI—CH₃COOH—H₂O and NaVO₃ —CH3COOTl—HNO₃—H_2O was investigated. The optimum conditions of the preparation of TIVO₃ and T₁₃V₅O₁₄ as well as the relations affecting the composition of the solid substances arising in the investigated systems were ascertained.

Full paper in Portable Document Format: 355a621.pdf

Chemical Papers 35 (5) 621–628 (1981)