ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Determination of kinetic data for the transformation of methylglyoxal

J. Königstein, D. Anderle, and M. Fedoroňko

Institute of Chemistry, Slovak Academy of Sciences, 809 33 Bratislava

 

Abstract:  The transformations of methylglyoxal, namely oxidation-reduction disproportionation into lactic acid and aldolization reactions, were investigated in alkaline medium (Na2CO3, NaOH) as a system of parallel reactions of the first and second order. The rate and catalytic constants were determined by a numerical calculation involving the method of least squares from polaro­graphie and potentiometrie investigations of the course of the transformation reactions.

Full paper in Portable Document Format: 354a471.pdf

 

Chemical Papers 35 (4) 471–479 (1981)

Wednesday, August 17, 2022

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