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Competitive intermolecular additions in the chemistry of ferrocene. II. Synthesis and cyclization of 1-(ω-benzoylalkanoyl)-1'-cinnamoylferrocenes

M. Sališová, Š. Toma, and E. Solčániová

Department of Organic Chemistry, Faculty of Natural Sciences, Komenský University, 816 31 Bratislava

 

Abstract:  ω-Benzoylalkanoyl ferrocenes (I, n =4—8) were acylated with cinnamoyl chloride and the prepared 1 -(ω-benzoylalkanyol)-1 '-cinnamoyl ferrocenes (II, n = 5—8) were submitted to base-catalyzed cyclization. In all cases, derivatives of [5]ferrocenophanes were the sole products.

Full paper in Portable Document Format: 344a507.pdf

 

Chemical Papers 34 (4) 507–513 (1980)

Wednesday, October 23, 2019

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