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Liquid junction potentials between aqueous and nonaqueous medium with different electrolytes

A. Kotočová

Department of Inorganic Chemistry, Slovak Technical University, 880 37 Bratislava

 

Abstract: The results of this study refer to the value of the liq. junction potential between aq. and nonaq. soln. of different electrolytes which was detd. on the basis of 1 of the extrathermodyn. assumptions (redox method) and to the factors influencing this value. Apparently. the ionic component of this liq. junction potential is relatively rather low and does not practically depend on the present nonaq. solvent. Irresp. of this fact, the solvent component of the liq. junction potential, which is given by interactions between solvents at the boundary, represents the substantial part of the liq. junction potential and the more different are the donor properties of the contacting solvents, the higher is its value.

Full paper in Portable Document Format: 341a56.pdf

 

Chemical Papers 34 (1) 56–62 (1980)

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