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Thermogravimetric and spectral study of some chloro(nitrile)titanium(III) complexes

M. Zikmund, A. Valent, and M. Kohútová

Institute of Inorganic Chemistry, Slovak Academy of Sciences, 809 34 Bratislava

 

Abstract: Titanium(III) chloride reacts with nitrile ligands to form the complexes TiCI3 3RCN (R = CH3, CH2 = CH, C6H5, C6H5CH2), and TiCl3 4CH3CN. The thermal decomposition reactions of these complexes were studied by thermogravimetric method in nitrogen atmosphere and under reduced pressure. The intermediates were isolated and identified by chemical and physical methods.

Full paper in Portable Document Format: 332a217.pdf

 

Chemical Papers 33 (2) 217–228 (1979)

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