ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

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Free radical polymerization in the presence of nonsolvents. II. Methyl methacrylate

J. Bartoň, I. Capek, and V. Juraničová

Polymer Institute, Slovak Academy of Sciences, 809 34 Bratislava

 

Abstract: The polymerization of methyl methacrylate (MMA) in methanol and in Θ mixtures formed from MMA—methanol, MMA—2-butanol, MMA—n -hexa­ne, and MMA—n -octane at 30°C was studied. The obtained values of the ratios kp/(kt)0,5 from stationary and kp/kt from the nonstationary kinetics of polymerization were discussed from the point of view of the effects of the preferential solvation and the polymer coil size on the kinetics of the polymerization in the system MMA—precipitant for poly(methyl methacry­late).

Full paper in Portable Document Format: 336a774.pdf

 

Chemical Papers 33 (6) 774–781 (1979)

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