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Paramagnetic species in the reactions of organometallic reagents. VI. High-resolution ESR spectra of anion radicals

A. Staško, A. Tkáč, Ľ. Malík, V. Adamčík, and M. Hronec

Institute of Chemical Physics, Department of Physical Chemistry, Slovak Technical University, 880 37 Bratislava

 

Abstract:  High-resolved electron spin resonance spectra of anion radicals of substrates as ketones, enolates of   β-diketones, quinones, sulfones, sulfoxides, nitro and cyano compounds, aromates and heteroaromates were obtained in a relatively simple procedure employing organometallic compounds as reduction agents. Experimental and simulated spectra are presented and some general aspects of this new method in the generation of anion radicals are discussed.

Full paper in Portable Document Format: 323a294.pdf

 

Chemical Papers 32 (3) 294–301 (1978)

Wednesday, May 29, 2024

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