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Reactions of saccharides catalyzed by molybdate ions. XXI. Preparation of some ω-deoxyaldoses

V. Bílik, L. Petruš, Ľ. Stankovič, and K. Linek

Institute of Chemistry, Slovak Academy of Sciences, 809 33 Bratislava

 

Abstract: 5-Deoxy-L-ribose, 6-deoxy-L-talose, 6-deoxy-D-talose, and 7-deoxy-L-glycero-L-taloheptose were prepd. by molybdate catalyzed epimerization of the corresponding epimeric aldoses. 5-Deoxy-L-arabinose was obtained by oxidn. of L-rhamnose with Pb(OAc)4. 7-Deoxy-L-glycero-L-galactoheptose and 7-deoxy-L-glycero-L-taloheptose were prepd. by nitromethane synthesis and oxidative decompn. of the corresponding nitroheptitols.

Full paper in Portable Document Format: 323a372.pdf

 

Chemical Papers 32 (3) 372–377 (1978)

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