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Application of the Haase functional relationship for activity to the systems with complete miscibility in both solid and liquid phase. Systems without common ion

M. Galová and M. Malinovský

Department of Mathematics, Faculty of Chemical Technology, Slovak Technical University, 880 37 Bratislava

 

Abstract: The math. and thermodn. anal. of the course of liquidus and solidus curves in binary systems of the 2nd kind (the systems formed by components MpAq-NrBt) was carried out. The existence of unlimited solid solns. was assumed. The activities of components of the system were estd. using the Haase (1969) relations. The limit values of slopes of the tangents to liquidus and solidus curves at the m.ps. of pure components as well as the general character of these systems were detd. The course of liquidus and solidus curves is practically the same regardless of that the activity is expressed by means of the Haase or Temkin relationships. However, utilizing Haase's approach the math. expressions are substantially simpler.

Full paper in Portable Document Format: 326a834.pdf

 

Chemical Papers 32 (6) 834–840 (1978)

Monday, July 13, 2020

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