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Furan derivatives. LXXXII. Effect of alkyl and aryl on physical and biological properties of alkyl 2-(5-nitrofuryl) and aryl 2-(5-nitrofuryl) ketones

M. Černayová, J. Kováč, P. Foltínová, and L. Ebringer

Department of Organic Chemistry, Slovak Technical University, 880 37 Bratislava

 

Abstract:  Synthesis of alkyl 2-(5-nitrofuryl) ketones (alkyl = methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl) and aryl 2-(5-nitrofuryl) ketones (aryl = phenyl, 2-thienyl, 5-nitro-2-pyrrolyl) by nitration of the corresponding alkyl and aryl 2-furyl ketones with acetyl nitrate is described. The wavenumber values of stretching vibration of the carbonyl group of alkyl 2-(5-nitrofuryl) ketones correlated with the Tafťs constants σ*. The synthesized compounds were tested for antibacterial and antifungal activities.

Full paper in Portable Document Format: 304a493.pdf

 

Chemical Papers 30 (4) 493–498 (1976)

Monday, June 24, 2024

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