ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Basicity of hydroxylamine and its derivatives

J. Mollin, F. Kašpárek, and J. Lasovský

Department of Inorganic and Physical Chemistry, Faculty of Natural Sciences, Palacký University, 771 46 Olomouc

 

Abstract: The рКа. values of hydroxylamine and its derivatives were determined titrimetrically in water and water — ethanol mixtures. The obtained  рКа values of the O-alkylhydroxylamines were correlated with the half-wave potentials of the Polarographie reduction waves. A surprisingly high рКа value of hydroxylamine was explained on the basis of the formation of hydrogen bonds with solvent proved by means of infrared spectra.

Full paper in Portable Document Format: 291a39.pdf

 

Chemical Papers 29 (1) 39–43 (1975)

Monday, September 16, 2019

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