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ISSN electronic edition: 1336-9075
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Proton magnetic resonance spectra of substituted phenylferrocenes. Transmission of the substituent effect into the particular positions in ferrocene and some metallocenes

Š. Toma, E. Solčániová, and A. Maholányiová

Department of Organic Chemistry, Faculty of Natural Sciences, Komenský University, 801 00 Bratislava

 

Abstract:  The p.m.r. spectra of 29 phenylferrocenes were recorded. Hammett's correlations δα, δß, δ1, vs. σ0 constants of substituents and δ = ϱIσIRσR were made with phenylferrocenes, substituted ferrocenes, cations of benzenecyclopentadienyl iron, cobalticinium salts, and substituted cymantrenes. The transmission of the substituent effects into the particul positions in ferrocene and further metallocenes is discussed.

Full paper in Portable Document Format: 294a526.pdf

 

Chemical Papers 29 (4) 526–532 (1975)

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