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Concentration vectors in phase diagrams

M. Malinovsk√Ĺ

Department of Inorganic Technology, Slovak Technical University, 880 37 Bratislava

 

Abstract: The method of concn. vectors and its application to phase diagrams of condensed isobaric and isothermal-isobaric systems is described. This method can explain several regularities tradionally expressed in denoted rules used for the characterization of phase diagrams, as e.g. the rule by van Rijn, the triangle, trapezoid, and tangent rules. In addn., the method of concn. vectors is successful even when some of these rules cannot be applied. Further, it is possible to det. the nature of crystn. processes occurring at invariant points of phase diagrams.

Full paper in Portable Document Format: 284a463.pdf

 

Chemical Papers 28 (4) 463–467 (1974)

Monday, May 23, 2022

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