ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

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 Study of the system V205—Na20. II. Physicochemical properties of the molten V205—NaV03 mixtures

V. Daněk, I. Votava, K. Matiašovský, and J. Balajka

Institute of Inorganic Chemistry, Slovak Academy of Sciences, 809 34 Bratislava

 

Abstract: The d., viscosity, and specific elec. cond. of the molten V2O5-NaVO3 mixts. in the temp. range 650-900°C were measured. In the range of existence of V bronze, Na0.235V2O5, a stable redox system VIV/VV is formed in the system which brings about a partial electronic conductance of the melt. The mechanism of V corrosion and the influence of the electronic cond. on the corrosion process are discussed.

Full paper in Portable Document Format: 286a728.pdf

 

Chemical Papers 28 (6) 728–732 (1974)

Wednesday, July 24, 2024

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