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ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7
Published monthly
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Alternative syntheses of methylated sugars. X. Methyl pyranosides of 2-O-methyl-D-glucose
P. Kováč and Ž. Longauerová
Institute of Chemistry, Slovak Academy of Sciences*
809 33 Bratislava
Abstract: Methyl 2-O-methyl-a-D-glucopyranoside and methyl 2 -0 -methyl -ß-D-glucopyranoside have been obtained in crystalline condition by methylation
of methyl 3-0-benzyl-4,6-0-benzylidene-
α,ß-D-glucopyranoside followed
by chromatography and removal of the blocking groups in the isolated
anomers. Debenzylidenation of methyl 3-0-benzyl-4,6-0-benzylidene-2-0-methyl-α-D-glucopyranoside, methylation and debenzylation afforded methyl
2,4,6-tri-O-methyl-α-D-glucopyranoside
Full paper in Portable Document Format: 273a415.pdf
Chemical Papers 27 (3) 415–420 (1973)
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