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Heterocyclic azo dyes as analytical reagents. III. Preparation and study of 1-(7-oxo-5,5-dimethyl-4,5,6,7-tetrahydrobenzothiazolyl-2-azo)-2-hydroxy-4,5-dimethylbenzene and its chelates with copper(II), cobalt(II), and nickel(II)

E. Kuchár, T. Tormová, and E. Martinovičová

Lehrstuhl für AnalytiscJie Chemie der Natumvissenschqftlichen Fakultät an der Komenský -Universität, 801 00 Bratislava

 

Abstract: 1-(7-Oxo-5,5-dimethyl-4,5,6,7-tetrahydrobenzothiazolyl-2-azo)-2-hydroxy-4,5-dimethylbenzene (I) was prepd. and its acid-base and complex-forming properties were studied. The compd. (I) forms complexes with Cu(II) in the ratio 1:1 and with Ni(II) in the ratio 2:1 in acidic media. The molar absorptivities, equil., and stability consts. were detd. by graphical and logarithmic anal. of pH curves.

Full paper in Portable Document Format: 274a461.pdf (in German)

 

Chemical Papers 27 (4) 461–466 (1973)

Monday, June 17, 2024

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