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Kinetics of the decomposition of benzoyl peroxide in poly(methyl methacrylate) at high pressures

R. Rado, F. Szöcs, M. Vinkovičová, and J. Plaček

Polymer Institute, Slovak Academy of Sciences, 809 34 Bratislava

 

Abstract:  Investigating the influence of pressure on the rate of the thermal decomposition of benzoyl peroxide in poly (methyl methacrylate) at 100°C, a reaction rate decrease, with pressure over the range 2 x 103 — 8 x 103 kp cm-2 was observed, the found value of the activation volume of this process being 7.5 cm3 mol-1 .

Full paper in Portable Document Format: 276a796.pdf

 

Chemical Papers 27 (6) 796–798 (1973)

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