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Isothiocyanates. XL. Reaction kinetics of isothiocyanates having a longer conjugated system with OH- anions and NH2 group of glycine

A. MartvoŇą and J. Sura

Department of Organic Chemistry, Slovak Technical University, 880 37 Bratislava

 

Abstract: The reactivity of isothiocyanates of conjugated stilbene, azobenzene, and diphenyl oxide systems with OH- anions and NH2 group of glycine was examined. The rate constants of addition, calculated from kinetic measurements, were correlated with σp constants of substituents. The electron transfer in the systems under study is discussed on the basis of comparison of the line slopes in particular systems.

Full paper in Portable Document Format: 276a811.pdf

 

Chemical Papers 27 (6) 811–815 (1973)

Monday, June 24, 2024

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