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Alternative Syntheses of Methylated Sugars. IV. Methyl Furanosides of 5-0-, 2,5-Di-O-, 3,5-Di-O- and 2,3,5-Tri-O-methyl-D-xylose

P. Kováč

Institute of Chemistry, Slovak Academy of Sciences, Bratislava 9

 

Abstract: Methyl furanosides of 5-0-, 2,5-di-O-, 3,5-di-O- and 2,3,5-tri-O-methyl-D-xylose have been synthesized starting from 1,2-O-isopropylidene-D-xylofuranose. The observed order of elution of the compounds under investigation proves that on silica gel the elution of methyl O-methyl-D-xylofuranosides follows the same pattern as known for gas chromatographic elution of methyl-О -methyl-glycopyranosides

Full paper in Portable Document Format: 256a460.pdf

 

Chemical Papers 25 (6) 460–466 (1971)

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