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On Phthalides and 1,3-Indandiones. XXXVI. Mercuration of Arylidenephthalides and 1,3-Indandiones by Mercury (II) Acetate

M. Lacová, F. Volna, E. Greiplová, and P. Hrnčiar

Department of Organic Chemistry, Faculty of Natural Sciences, Komenský University, Bratislava 1

 

Abstract: The mercuration by mercury(II) acetate proceeds as an addition and substitution reaction in the case of benzalphthalide, as a substitution reaction in the case of 3-(1-naphthal)phthalide and predominantly as an addition reaction in the case of 3-(2-naphthal)phthalide. 2-Brom-1,3-indandione is substituted in position 2 while 2-aryl-l,3-indandiones give some instable complexes.

Full paper in Portable Document Format: 244a309.pdf

 

Chemical Papers 24 (4) 309–313 (1970)

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