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ISSN electronic edition: 1336-9075
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Spectral and Magnetochemical Investigation of Titanium (III) Chloro Alkoxy Complexes with Aliphatic Alcohols

M. Zikmund, Ľ. Štepničková, and M. Kohútová

Institute of Inorganic Chemistry, Slovak Academy of Sciences, Bratislava 9

 

Abstract: On the basis of magnetic measurements, absorption, diffusion-reflectance, and infrared spectra of the complexes TiCl3 • 4CH3OH, TiCl3 • 5CH3OH, and products of their thermal decomposition, the conclusions are drawn about the stereochemistries of these compounds in solid state and in tetrahydrofuran solution as well. Both above mentioned complexes possess structures řrawe-[TiCl2(CH3OH)4]Cl and [TiCl(CH3OH)5]Cl2, while the products of their thermal decomposition are coordination polymers in which methoxide bridges occur.

Full paper in Portable Document Format: 2311-12a856.pdf

 

Chemical Papers 23 (11-12) 856–860 (1969)

Tuesday, June 18, 2024

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