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Isothiocyanates. XXV. Synthesis, Infra-red and Ultra-violet Spectra of Isothiocyanatodiphenyloxides

A. Martvoň and K. Antoš

Department of Organic Chemistry, Slovak Technical University, Bratislava 1

 

Abstract:  In this paper, the synthesis of a series of 4-substituted derivatives of 4-isothiocyanatodiphenyloxide is described. The NC S group is influenced by substituents to a small extent only ( ρ = —15.8) when compared with other conductive systems as can be concluded from the correlation of absorption maxima vas(NCS) in the 2060 cm-1 range with the Hammett ov constant of the substituent. The evaluation of the mutual interaction is also based on ultra-violet spectra.

Full paper in Portable Document Format: 233a181.pdf

 

Chemical Papers 23 (3) 181–186 (1969)

Wednesday, October 16, 2019

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