ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
Registr. No.: MK SR 9/7

Published monthly
 

Diels-Alder reaction of alkylcyclopentadienes and dienophiles of the aeryl type. II. Reactions with methyl vinyl ketone

E. Holbová and J. Hrivňák

Chemisches Institut der Komenský-Universität, Bratislava 1

 

Abstract: The synthesis of bicyclic ketones was effected by the reaction of mainly 1-alkylcyclopentadienes with methyl vinyl ketone. As was found by gas chromatography, the adduct of 1-ethylcyclopentadiene with methyl vinyl ketone is a mixture of endo and exo isomers of 1-ethyl-5-acetylbicyclo[2,2,1]-2-heptene and 1-ethyl-6-acetylbicyclo[2,2,1]-2-heptene. The endo and exo isomers in the reaction mixture were identified by isomerization in the presence of sodium ethoxide.

Full paper in Portable Document Format: 238a611.pdf (in German)

 

Chemical Papers 23 (8) 611–615 (1969)

Monday, May 27, 2024

IMPACT FACTOR 2021
2.146
SCImago Journal Rank 2021
0.365
SEARCH
Advanced
VOLUMES
European Symposium on Analytical Spectrometry ESAS 2022
© 2024 Chemical Papers