ISSN print edition: 0366-6352
ISSN electronic edition: 1336-9075
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Gravimetric determination of cadmium with β-resorcylidene thiosemicarbazone

S. Stankoviansky, J. Čársky, A. Beňo, and E. Dolníková

Department of Analytical Chemistry, Faculty of Natural Sciences, Komenský University, Bratislava

 

Abstract: The solubility product of the cadmium salt of the reagent was determined in dependence on pH and it has been found that the optimal conditions are at pH 6.5—8.5. Cadmium is weighed either in the form of Cd(C8H802N3S)2 or as a monohydrate. The presence of the alkali metal cations, Mg2+, Cu2+, Sr2+, Ba2+, As(III), As(V), NH4+ and of smaller amounts of Zn2+ do not interfere with the determination.

Full paper in Portable Document Format: 221a50.pdf (in Slovak)

 

Chemical Papers 22 (1) 50–55 (1968)

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