ISSN print edition: 0366-6352 ISSN electronic edition: 1336-9075 Registr. No.: MK SR 9/7 Published monthly

Synthesis and the thermogravimetric investigation of complexes of titanium(III) chloride with aliphatic alcohols

M. Zikmund, Ľ. Štepničková, and K. Hrnčiarová

Institut für anorganische Chemie der Slowakischen Akademie der Wissenschaften, Bratislava

Abstract: The solid complexes TiCl₃.4MeOH, TiCl₃.4EtOH, TiCl₃.3PrOH, TiCl₃.3iso-PrOH, and TiCl₃.3iso-BuOH were prepd. from TiCl3 and the aliphatic alcs. and analyzed thermogravimetrically. Powd. H₂O-free TiCl₃ is ground with 0.25-1M alc. in hexane, heptane, or C₆H₆ in a rotating glass ball reactor for 1-10 hrs., depending on the type of alc. Thermogravimetric anal. of TiCl₃.5MeOH and TiCl₃.4iso-PrOH under N atm. and reduced pressure indicates that there is a partial alcoholysis with a formation of Ti(III) haloalkoxides.

Full paper in Portable Document Format: 2212a917.pdf (in German)

Chemical Papers 22 (12) 917–928 (1968)