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D.C. Conduction Phenomenon of Some Rhodanine Azo Complexes

M. S. Aziz, A. Z. El-Sonbati, and A. S. Hilali

Department of Physics, Faculty of Science (Demiatta), Mansoura University, Demiatta, Egypt

 

Received: 12 November 2001

Abstract: The electrical behaviour of 5-(4-R-phenylazo)-3-phenyl-2-thioxothiazolidin-4-one compounds and their complexes with Co2+, Cu2+, and UO22+ was investigated in the temperature range 300—450 K. The conductivities were found to depend on the structure of the compounds and the metal ions. Both the structures of the azo and the complexation process play an effective role in the conduction process. The activation energy, ΔE, increases by decreasing the conductivity of the complexes.

Full paper in Portable Document Format: 565a305.pdf

 

Chemical Papers 56 (5) 305–308 (2002)

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